Arsenate removal from aqueous solution using chitosan-coated bentonite, chitosan-coated kaolinite and chitosan-coated sand: parametric, isotherm and thermodynamic studies

doi:10.2166/wst.2018.339

Chia Nan University of Pharmacy & Science Institutional Repository > 環境永續學院 > 環境工程與科學系(所) > 期刊論文 > Item 310902800/32226

Please use this identifier to cite or link to this item: http://ir.cnu.edu.tw/handle/310902800/32226

標題:	Arsenate removal from aqueous solution using chitosan-coated bentonite, chitosan-coated kaolinite and chitosan-coated sand: parametric, isotherm and thermodynamic studies
作者:	Futalan, Cybelle M. Huang, Yu-Shen Chen, Jheng-Hong Wan, Meng-Wei
貢獻者:	Natl Res Ctr Disaster Free & Safe Ocean City Chia Nan Univ Pharm & Sci, Dept Environm Engn & Sci Natl Cheng Kung Univ, Dept Resources Engn Chia Nan Univ Pharm & Sci, Dept Environm Resources Management
關鍵字:	arsenate bentonite chitosan kaolinite sand thermodynamics
日期:	2018-08
上傳時間:	2019-11-15 15:45:53 (UTC+8)
出版者:	IWA PUBLISHING
摘要:	In the present work, the removal efficiency of As(V) from aqueous solution using chitosan-coated bentonite (CCB), chitosan-coated kaolinite (CCK) and chitosan-coated sand (CCS) was evaluated. The chitosan-based adsorbents were characterized using scanning electron microscopy, Fourier-transform infrared spectroscopy, the Brunauer-Emmett-Teller method and thermogravimetric analysis. Kinetic studies revealed that As(V) uptake using CCB, CCK and CCS fitted well with the pseudo-second order equation (R-2 >= 0.9847; RMSE <= 9.1833). Equilibrium data show good correlation with the Langmuir model (R-2 >= 0.9753; RMSE <= 8.5123; SSE <= 16.2651) for all adsorbents, which implies monolayer coverage onto homogenous energy sites. The Langmuir adsorption capacity for As (V) at pH 7.0 was determined to be 67.11, 64.85, and 16.78 mg/g for CCB, CCK and CCS, respectively. Thermodynamic studies show that As(V) uptake is exothermic in nature using CCK and endothermic using CCB and CCS. Moreover, adsorption of As(V) was feasible and spontaneous for CCB and CCS at 298 to 328 K. Results show that CCB is the most effective adsorbent in the removal of As(V) from water due to its high surface area and large pore diameter.
link:	http://dx.doi.org/10.2166/wst.2018.339
關聯:	Annals of Dermatology, v.78, n.3, pp.676-689
Appears in Collections:	[環境工程與科學系(所)] 期刊論文 [環境資源管理系(所)] 期刊論文

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