Chia Nan University of Pharmacy & Science Institutional Repository:Item 310902800/32226
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    標題: Arsenate removal from aqueous solution using chitosan-coated bentonite, chitosan-coated kaolinite and chitosan-coated sand: parametric, isotherm and thermodynamic studies
    作者: Futalan, Cybelle M.
    Huang, Yu-Shen
    Chen, Jheng-Hong
    Wan, Meng-Wei
    貢獻者: Natl Res Ctr Disaster Free & Safe Ocean City
    Chia Nan Univ Pharm & Sci, Dept Environm Engn & Sci
    Natl Cheng Kung Univ, Dept Resources Engn
    Chia Nan Univ Pharm & Sci, Dept Environm Resources Management
    關鍵字: arsenate
    bentonite
    chitosan
    kaolinite
    sand
    thermodynamics
    日期: 2018-08
    上傳時間: 2019-11-15 15:45:53 (UTC+8)
    出版者: IWA PUBLISHING
    摘要: In the present work, the removal efficiency of As(V) from aqueous solution using chitosan-coated bentonite (CCB), chitosan-coated kaolinite (CCK) and chitosan-coated sand (CCS) was evaluated. The chitosan-based adsorbents were characterized using scanning electron microscopy, Fourier-transform infrared spectroscopy, the Brunauer-Emmett-Teller method and thermogravimetric analysis. Kinetic studies revealed that As(V) uptake using CCB, CCK and CCS fitted well with the pseudo-second order equation (R-2 >= 0.9847; RMSE <= 9.1833). Equilibrium data show good correlation with the Langmuir model (R-2 >= 0.9753; RMSE <= 8.5123; SSE <= 16.2651) for all adsorbents, which implies monolayer coverage onto homogenous energy sites. The Langmuir adsorption capacity for As (V) at pH 7.0 was determined to be 67.11, 64.85, and 16.78 mg/g for CCB, CCK and CCS, respectively. Thermodynamic studies show that As(V) uptake is exothermic in nature using CCK and endothermic using CCB and CCS. Moreover, adsorption of As(V) was feasible and spontaneous for CCB and CCS at 298 to 328 K. Results show that CCB is the most effective adsorbent in the removal of As(V) from water due to its high surface area and large pore diameter.
    link: http://dx.doi.org/10.2166/wst.2018.339
    關聯: Annals of Dermatology, v.78, n.3, pp.676-689
    显示于类别:[環境工程與科學系(所)] 期刊論文
    [環境資源管理系(所)] 期刊論文

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