| 標題: | Mixed-Valence Properties in L-type Complexes |
| 作者: | Ju-Ling Lin(林如玲)
Yuan Jang Chen(陳元璋) |
| 貢獻者: | Department of Chemistry, Fu Jen Catholic University |
| 關鍵字: | mixed-valence chemistry
intervalence transfer
superexchange coupling |
| 日期: | 2008-07 |
| 上傳時間: | 2017-12-04 15:54:47 (UTC+8) |
| 摘要: | Mixed-Valance chemistry in ruthenium is the transition metal choice to study electron transfer or exchange because low spin d5-d6 center from relatively stable coordinate complexes.1-3 Hush published the well-known basis of mixed-valence chemistry which focused on the two-state model.4 Creutz, Newton and Sutin reported a new aspect of the superexchange coupling model with the three-state system.5,6 Few reports provided significant points of real systems for superexchange coupling.7-9 The focus of this report is the synthesis and study of L-type tri-ruthenium complexes that exhibit interesting intervalence absorption and strong comproportionation between terminal metal centers. The electochemistry of △E1/2 between terminal centers for RU3(1) and Ru3(2) ranged between 0.12 and 0.13V. |
| 關聯: | 第五屆海峽化學、生物及材料研討會，起迄日：2008/07/21-2008/07/22，地點：嘉南藥理科技大學 |
| 显示于类别: | [藥理學院] 2008第五屆海峽化學、生物及材料研討會
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