Mixed-Valence Properties in L-type Complexes

Chia Nan University of Pharmacy & Science Institutional Repository > 藥理學院 > 2008第五屆海峽化學、生物及材料研討會 > Item 310902800/30488

jsp.display-item.identifier=請使用永久網址來引用或連結此文件: https://ir.cnu.edu.tw/handle/310902800/30488

標題:	Mixed-Valence Properties in L-type Complexes
作者:	Ju-Ling Lin(林如玲) Yuan Jang Chen(陳元璋)
貢獻者:	Department of Chemistry, Fu Jen Catholic University
關鍵字:	mixed-valence chemistry intervalence transfer superexchange coupling
日期:	2008-07
上傳時間:	2017-12-04 15:54:47 (UTC+8)
摘要:	Mixed-Valance chemistry in ruthenium is the transition metal choice to study electron transfer or exchange because low spin d5-d6 center from relatively stable coordinate complexes.1-3 Hush published the well-known basis of mixed-valence chemistry which focused on the two-state model.4 Creutz, Newton and Sutin reported a new aspect of the superexchange coupling model with the three-state system.5,6 Few reports provided significant points of real systems for superexchange coupling.7-9 The focus of this report is the synthesis and study of L-type tri-ruthenium complexes that exhibit interesting intervalence absorption and strong comproportionation between terminal metal centers. The electochemistry of △E1/2 between terminal centers for RU3(1) and Ru3(2) ranged between 0.12 and 0.13V.
關聯:	第五屆海峽化學、生物及材料研討會，起迄日：2008/07/21-2008/07/22，地點：嘉南藥理科技大學
显示于类别:	[藥理學院] 2008第五屆海峽化學、生物及材料研討會

文件中的档案:

档案	描述	大小	格式	浏览次数
C08.pdf		345Kb	Adobe PDF	274	检视/开启

在CNU IR中所有的数据项都受到原著作权保护.

TAIR相关文章