Mixed-Valence Properties in L-type Complexes

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Title:	Mixed-Valence Properties in L-type Complexes
Authors:	Ju-Ling Lin(林如玲) Yuan Jang Chen(陳元璋)
Contributors:	Department of Chemistry, Fu Jen Catholic University
Keywords:	mixed-valence chemistry intervalence transfer superexchange coupling
Date:	2008-07
Issue Date:	2017-12-04 15:54:47 (UTC+8)
Abstract:	Mixed-Valance chemistry in ruthenium is the transition metal choice to study electron transfer or exchange because low spin d5-d6 center from relatively stable coordinate complexes.1-3 Hush published the well-known basis of mixed-valence chemistry which focused on the two-state model.4 Creutz, Newton and Sutin reported a new aspect of the superexchange coupling model with the three-state system.5,6 Few reports provided significant points of real systems for superexchange coupling.7-9 The focus of this report is the synthesis and study of L-type tri-ruthenium complexes that exhibit interesting intervalence absorption and strong comproportionation between terminal metal centers. The electochemistry of △E1/2 between terminal centers for RU3(1) and Ru3(2) ranged between 0.12 and 0.13V.
Relation:	第五屆海峽化學、生物及材料研討會，起迄日：2008/07/21-2008/07/22，地點：嘉南藥理科技大學
Appears in Collections:	[Pharmacy and Science] The 5rh Conference of Channel-bridge Chemistry, Biology and materal Science

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