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| 標題: | Positron annihilation spectroscopic study on fine-structure characterization and ethanol dehydration by pervaporation for interfacially polymerized composite membranes |
| 作者: | Chao, Wei-Chi
Huang, Shu-Hsien
Wei, Shi-Wei
Huang, Yun-Hsuan
Liao, Kuo-Sung
Lai, Cheng-Lee
Tsai, Hui-An
Lee, Kueir-Rarn |
| 貢獻者: | 環境工程與科學系 |
| 關鍵字: | Pervaporation
Interfacial Polymerization
Positron Annihilation Lifetime Spectroscopy (Pals) |
| 日期: | 2013-02 |
| 上傳時間: | 2014-05-26 10:48:22 (UTC+8) |
| 出版者: | Elsevier Science Bv |
| 摘要: | In this study, polyamide (PA) composite membranes (DMDPA-TMC/CA, NTEA-TMC/CA, DETA-TMC/CA) were prepared through the interfacial polymerization reaction between a trimesoyl chloride (TMC) and each of the following three amines: 3,3-diamino-N-methyl-dipropylamine (DMDPA), nitrilotriethylamine (NTEA), and diethylenetriamine (DETA), on the surface of an asymmetric cellulose acetate (CA) membrane. The effects of the amine chemical structure and the interfacial polymerization conditions on the dehydration of an aqueous ethanol solution by pervaporation were investigated. To characterize the swelling behavior and the resulting free volume variation in the interfacially polymerized PA layers, the PA membranes in dry and wet (with aqueous ethanol solution) conditions were probed by positron annihilation lifetime spectroscopy (PALS). The difference between the o-Ps lifetime in the wet and that in the dry condition (Delta tau(3)=tau(3w)-tau(3d)) of the interfacially polymerized PA membranes increased in the following order: DETA-TMC < DMDPA-TMC < NTEA-TMC. The swelling effect induced by the aqueous ethanol solution was restricted by the crosslinking structure in the PA layer. This result corresponded well with that of the XPS analysis. The DETA-TMC/CA composite membrane prepared using the desirable interfacial polymerization conditions (immersion in the aqueous solution of 0.5 wff DETA for 10 s, and contact with the organic solution of 0.5 wff TMC for 5 s) exhibited the following desirable pervaporation performance in dehydrating an aqueous solution of 90 wt% ethanol at 25 degrees C: a permeation flux of 1220 g/m(2) h and a water concentration in permeate of 98.4 wt%. It was also found that the DETA-TMC/CA composite membrane exhibited superior performance compared to the composite membranes discussed in the literature. (C) 2012 Elsevier B.V. All rights reserved. |
| 關聯: | Journal of Membrane Science, v.429, pp.34-43 |
| 顯示於類別: | [環境工程與科學系(所)] 期刊論文
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