Positron annihilation spectroscopic study on fine-structure characterization and ethanol dehydration by pervaporation for interfacially polymerized composite membranes

doi:10.1016/j.memsci.2012.11.020

CNU IR > College of Sustainable Environment and Recreation > Dept. of Environmental Engineering and Science (including master's program) > Periodical Articles > Item 310902800/27903

Please use this identifier to cite or link to this item: https://ir.cnu.edu.tw/handle/310902800/27903

Title:	Positron annihilation spectroscopic study on fine-structure characterization and ethanol dehydration by pervaporation for interfacially polymerized composite membranes
Authors:	Chao, Wei-Chi Huang, Shu-Hsien Wei, Shi-Wei Huang, Yun-Hsuan Liao, Kuo-Sung Lai, Cheng-Lee Tsai, Hui-An Lee, Kueir-Rarn
Contributors:	環境工程與科學系
Keywords:	Pervaporation Interfacial Polymerization Positron Annihilation Lifetime Spectroscopy (Pals)
Date:	2013-02
Issue Date:	2014-05-26 10:48:22 (UTC+8)
Publisher:	Elsevier Science Bv
Abstract:	In this study, polyamide (PA) composite membranes (DMDPA-TMC/CA, NTEA-TMC/CA, DETA-TMC/CA) were prepared through the interfacial polymerization reaction between a trimesoyl chloride (TMC) and each of the following three amines: 3,3-diamino-N-methyl-dipropylamine (DMDPA), nitrilotriethylamine (NTEA), and diethylenetriamine (DETA), on the surface of an asymmetric cellulose acetate (CA) membrane. The effects of the amine chemical structure and the interfacial polymerization conditions on the dehydration of an aqueous ethanol solution by pervaporation were investigated. To characterize the swelling behavior and the resulting free volume variation in the interfacially polymerized PA layers, the PA membranes in dry and wet (with aqueous ethanol solution) conditions were probed by positron annihilation lifetime spectroscopy (PALS). The difference between the o-Ps lifetime in the wet and that in the dry condition (Delta tau(3)=tau(3w)-tau(3d)) of the interfacially polymerized PA membranes increased in the following order: DETA-TMC < DMDPA-TMC < NTEA-TMC. The swelling effect induced by the aqueous ethanol solution was restricted by the crosslinking structure in the PA layer. This result corresponded well with that of the XPS analysis. The DETA-TMC/CA composite membrane prepared using the desirable interfacial polymerization conditions (immersion in the aqueous solution of 0.5 wff DETA for 10 s, and contact with the organic solution of 0.5 wff TMC for 5 s) exhibited the following desirable pervaporation performance in dehydrating an aqueous solution of 90 wt% ethanol at 25 degrees C: a permeation flux of 1220 g/m(2) h and a water concentration in permeate of 98.4 wt%. It was also found that the DETA-TMC/CA composite membrane exhibited superior performance compared to the composite membranes discussed in the literature. (C) 2012 Elsevier B.V. All rights reserved.
Relation:	Journal of Membrane Science, v.429, pp.34-43
Appears in Collections:	[Dept. of Environmental Engineering and Science (including master's program)] Periodical Articles

Files in This Item:

File	Description	Size	Format
index.html		0Kb	HTML	1943	View/Open

Loading...