| 標題: | An Efficient One-Pot Synthesis of p-Enamino Ketones from Endo Glucal via Hypervalent Iodine |
| 作者: | Zi-Ping Lin (林子平)
Hui-Chang Lin
Hsu-HsuanWu
Hsiu-Wen Chou
Shih-Hao Liu
Su-I Wang
Shao-Kai Lin
Kuan-Chin Sung
Fung Fuh Wong |
| 日期: | 2011 |
| 上傳時間: | 2011-06-23 14:56:47 (UTC+8) |
| 摘要: | β-Enamino ketones were successfully synthesized by reacting endo glucals with hypervalent iodine and primary or secondary amines in one-pot reaction. After oxidation and protonation on hypervalent iodine agent in acidic condition, endo glucals effectively were converted to uncyclic β-alkoxyvinyl ketones. Following the further substitution with primary or secondary amines, the corresponding β-enamino ketone derivatives were obtained in 57-67 % yields. |
| 關聯: | 2011年台俄有機、藥物與生物化學交流暨藥物化學研討會，起迄日：2011/04/06~2011/04/05，地點：溪頭台大實驗林 |
| 顯示於類別: | [藥理學院] 2011年台俄有機、藥物與生物化學交流暨藥物化學研討會
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