An Efficient One-Pot Synthesis of p-Enamino Ketones from Endo Glucal via Hypervalent Iodine

CNU IR > Pharmacy and Science > 2011 Taiwanese-Russian Organic, Medicinal and Bio Chemistry Interactions & PST Medicinal Chemistry Symposium > Item 310902800/24190

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题名:	An Efficient One-Pot Synthesis of p-Enamino Ketones from Endo Glucal via Hypervalent Iodine
作者:	Zi-Ping Lin (林子平) Hui-Chang Lin Hsu-HsuanWu Hsiu-Wen Chou Shih-Hao Liu Su-I Wang Shao-Kai Lin Kuan-Chin Sung Fung Fuh Wong
日期:	2011
上传时间:	2011-06-23 14:56:47 (UTC+8)
摘要:	β-Enamino ketones were successfully synthesized by reacting endo glucals with hypervalent iodine and primary or secondary amines in one-pot reaction. After oxidation and protonation on hypervalent iodine agent in acidic condition, endo glucals effectively were converted to uncyclic β-alkoxyvinyl ketones. Following the further substitution with primary or secondary amines, the corresponding β-enamino ketone derivatives were obtained in 57-67 % yields.
關聯:	2011年台俄有機、藥物與生物化學交流暨藥物化學研討會，起迄日：2011/04/06~2011/04/05，地點：溪頭台大實驗林
显示于类别:	[Pharmacy and Science] 2011 Taiwanese-Russian Organic, Medicinal and Bio Chemistry Interactions & PST Medicinal Chemistry Symposium

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