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    Please use this identifier to cite or link to this item: https://ir.cnu.edu.tw/handle/310902800/21720


    標題: Efficient Synthesis of 4,5-Disubstituted-3-toluenesulfonyl Glutarimides. Application to the Formal Synthesis of Mappicine Ketone
    作者: Yung-Sheng Wang
    Nein-Chen Chang
    Ching-Han Lin
    Huo-Mu Tai
    貢獻者: 醫藥化學系
    關鍵字: Ethyl α
    β-disubstituted acrylate esters
    [3+3] Annulation
    Mappicine ketone
    日期: 2008-04
    上傳時間: 2009-10-13 09:09:28 (UTC+8)
    出版者: Chinese Chemical Soc
    摘要: Various 4,5-disubstituted-3-sulfonyl glutarimides 3 were synthesized from α-sulfonyl acetamide 1 and ethyl α,β-disubstituted acrylate esters 2 via stepwise facile [3+3] annulation in moderate yield. The synthesis of pyridin-2-one 9, a key intermediate for mappicine ketone (4) synthesis, was also reported.
    關聯: Journal of the Chinese Chemical Society 55(2):p.431-434
    Appears in Collections:[食藥產業暨檢測科技系(含五專)] 期刊論文

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