本計畫之起始劑FcXCH/sub 2/CH/sub 2/P.phi./sub 2/(X=S,O)之氧化還原控制的開關配位子及Fe/sup I/Cp(C/sub 6/H/sub 6/)PF/sub 6/的過渡金屬錯化物都先由Ferrocene合成而得。並先進行以鈉汞齊還原Fe/sup I/ Cp(C/sub 6/H/sub 6/)PF/sub 6/之反應,後才將配位子慢慢加入,反應得到一黃色的配位化合物。並初步以元素分析及核磁共振光譜探討其分子結構。 A series of containing Redox-switchable hemilable ligands, FcXCH/sub 2/CH/sub 2/P.phi./sub 2/ (X=S,O), and the iron metal complex, [FeCp(C/sub 6/H/sub 6/)]/sup +/[PF/sub 6/]/sup -/, are synthesized from ferrocene in this work. Further, a coordination reaction of FcXCH/sub 2/CH/sub 2/P.phi./sub 2/ with a nineteen electrons iron metal complex, which is reduced from [FeCp(C/sub 6/H/sub 6/)]/sup +/[PF/sub 6/]/sup -/ with sodium amalgam, give a yellow color product. The preliminary structure of product is determined with Elemental analysis, and NMR spectra.
