含氧化還原控制配位子之鐵、釕金屬錯化物的合成與結構探討

CNU IR > Pharmacy and Science > Dept. of Cosmetic Science and institute of cosmetic science > MOST Project > Item 310902800/1894

Please use this identifier to cite or link to this item: https://ir.cnu.edu.tw/handle/310902800/1894

Title:	含氧化還原控制配位子之鐵、釕金屬錯化物的合成與結構探討 Preparation, Characterization of Fe, Ru Complex with Redox-Switchable Ligands
Authors:	王東亮 Dong-Liang Wang
Contributors:	化妝品應用與管理系
Keywords:	鐵錯合物釕配位基氧化還原 Iron Complex Ruthenium Ligand Redox
Date:	1999
Issue Date:	2008-07-18 16:23:22 (UTC+8)
Publisher:	台南縣：嘉南藥理科技大學化妝品應用與管理系
Abstract:	本計畫之起始劑FcXCH/sub 2/CH/sub 2/P.phi./sub 2/(X=S,O)之氧化還原控制的開關配位子及Fe/sup I/Cp(C/sub 6/H/sub 6/)PF/sub 6/的過渡金屬錯化物都先由Ferrocene合成而得。並先進行以鈉汞齊還原Fe/sup I/ Cp(C/sub 6/H/sub 6/)PF/sub 6/之反應,後才將配位子慢慢加入,反應得到一黃色的配位化合物。並初步以元素分析及核磁共振光譜探討其分子結構。 A series of containing Redox-switchable hemilable ligands, FcXCH/sub 2/CH/sub 2/P.phi./sub 2/ (X=S,O), and the iron metal complex, [FeCp(C/sub 6/H/sub 6/)]/sup +/[PF/sub 6/]/sup -/, are synthesized from ferrocene in this work. Further, a coordination reaction of FcXCH/sub 2/CH/sub 2/P.phi./sub 2/ with a nineteen electrons iron metal complex, which is reduced from [FeCp(C/sub 6/H/sub 6/)]/sup +/[PF/sub 6/]/sup -/ with sodium amalgam, give a yellow color product. The preliminary structure of product is determined with Elemental analysis, and NMR spectra.
Relation:	計畫編號:NSC88-2113-M041-004
Appears in Collections:	[Dept. of Cosmetic Science and institute of cosmetic science] MOST Project

Files in This Item:

File	Description	Size	Format
NSC88-2113-M041-004.pdf		168Kb	Adobe PDF	449	View/Open

Loading...