Chia Nan University of Pharmacy & Science Institutional Repository:Item 310902800/488
English  |  正體中文  |  简体中文  |  全文笔数/总笔数 : 17776/20117 (88%)
造访人次 : 10878590      在线人数 : 437
RC Version 7.0 © Powered By DSPACE, MIT. Enhanced by NTU Library IR team.
搜寻范围 查询小技巧:
  • 您可在西文检索词汇前后加上"双引号",以获取较精准的检索结果
  • 若欲以作者姓名搜寻,建议至进阶搜寻限定作者字段,可获得较完整数据
  • 进阶搜寻


    標題: 化粧品用之高分散型奈米碳黑之研發與評估
    作者: 李佳芬
    貢獻者: 化粧品應用與管理系
    日期: 2006
    上傳時間: 2008-05-19 09:43:22 (UTC+8)
    出版者: 台南縣:嘉南藥理科技大學化粧品應用與管理系
    摘要: The purpose of this study was to modify the surface characteristics of CB so as to prevent the aggregation of CB to provide the dispersibilities in either H2O or organic solvent. In this study, five kinds of hydrophilic TEMPO-terminated polymer, hydrophobic TEMPO-terminated polymer and amphiphilic TEMPO-terminated block copolymer were synthesized. The five kinds of TEMPO-terminated polymers were: (1) poly(4-acetoxystyrene) (PAS-T) (2) poly(4-hydroxystyrene) (PHS-T) (3) polystyrene (PS-T) (4) poly(4-acetoxystyrene)-block-polystyrene (PAS-b-PS-T) (5) poly(4-hydroxystyrene)-block-polystyrene (PHS-b-PS-T). These TEMPO-terminated polymers with desired molecular weights and specific structures were synthesized by using the method of living radical polymerization in the presence of 2,2,6,6-tetramethylpiperidinyl-1-oxy (TEMPO). These TEMPO-terminated polymers and TEMPO-terminated block copolymers were grafted onto the surface of CB through a reaction of polymer radicals trapped by CB, so as to obtain the TEMPO-terminated polymer / CB and TEMPO-terminated block copolymer / CB composite nanoparticles. Various variables such as reaction time, reaction temperature, amount of TEMPO-terminated polymer, molecular weight of TEMPO-terminated polymer and amount of CB all of which influenced the grafting efficiency were investigated. Besides, the stability of the composite nanoparticles, which dispersed in H2O or organic solvent, was investigated by laser light scattering. The amphiphilic composite nanoparticles, PHS-T/CB and PHS-b-PS-T/CB, which dispersed well in both H2O and organic solvent, were synthesized successfully in this work.
    關聯: 計畫編號 : CNCS9507
    显示于类别:[化妝品應用與管理系(所)] 校內計畫


    档案 描述 大小格式浏览次数
    95CNCS9507.pdf171KbAdobe PDF793检视/开启

    在CNU IR中所有的数据项都受到原著作权保护.


    DSpace Software Copyright © 2002-2004  MIT &  Hewlett-Packard  /   Enhanced by   NTU Library IR team Copyright ©   - 回馈