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    Please use this identifier to cite or link to this item: http://ir.cnu.edu.tw/handle/310902800/32590

    標題: Graphene oxide functionalized with zwitterionic copolymers as selective layers in hybrid membranes with high pervaporation performance
    作者: Ang, Micah Belle Marie Yap
    Gallardo, Marwin R.
    Dizon, Gian Vincent C.
    De Guzman, Manuel Reyes
    Tayo, Lemmuel L.
    Huang, Shu-Hsien
    Cheng-Lee Lai(賴振立)
    Tsai, Hui-An
    Hung, Wei-Song
    Hu, Chien-Chieh
    Chang, Yung
    Lee, Kueir-Rarn
    貢獻者: Chung Yuan Christian Univ, Dept Chem Engn, R&D Ctr Membrane Technol
    Mapua Univ, Sch Chem Biol & Mat Engn & Sci
    Sichuan Univ Sci & Engn, Mat Corros & Protect Key Lab Sichuan Prov, Coll Mat Sci & Engn
    Natl Ilan Univ, Dept Chem & Mat Engn
    Chia Nan Univ Pharm & Sci, Dept Environm Engn & Sci
    Natl Taiwan Univ Sci & Technol, Grad Inst Appl Sci & Technol
    關鍵字: Graphene oxide
    Pressure-assisted filtration
    日期: 2019-10
    上傳時間: 2020-07-29 13:51:08 (UTC+8)
    摘要: Zwitterionic copolymers, poly(glycidyl methacrylate-sulfobetaine methacrylate) [poly(GMA-SBMA)], was incorporated into graphene oxide (GO) to form a GO-poly(GMA-SBMA) framework. This compound was then deposited onto a polysulfone support through pressure-assisted filtration to fabricate hybrid membranes. Optimum fabrication conditions were determined by varying the poly(GMA-SBMA) loading. Attenuated total reflectance-Fourier transform infrared and X-ray photoelectron spectroscopy confirmed the covalent bonding between poly(GMA-SBMA) and GO. On account of loading incremental amounts of poly(GMA-SBMA), the membrane thickness was increased (illustrated by field emission scanning electron microscopic images), the interlayer spacing between GO sheets was expanded (shown by X-ray diffraction patterns), and the membrane hydrophilic properties were enhanced (indicated by water contact angle data). Relative to the pristine GO membrane, hybrid membranes fabricated at optimum conditions exhibited superior separation performance (99.60 wt% water concentration in permeate and 1102 gm(-2).h(-1) permeation flux) on dehydrating a 70 wt% aqueous isopropanol solution by pervaporation. This present study explored the potential of poly(GMA-SBMA) for developing hybrid membranes with excellent pervaporation performance.
    關聯: Journal of Membrane Science, v.587, UNSP 117188
    Appears in Collections:[環境工程與科學系(所)] 期刊論文

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