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| 標題: | Graphene oxide functionalized with zwitterionic copolymers as selective layers in hybrid membranes with high pervaporation performance |
| 作者: | Ang, Micah Belle Marie Yap
Gallardo, Marwin R.
Dizon, Gian Vincent C.
De Guzman, Manuel Reyes
Tayo, Lemmuel L.
Huang, Shu-Hsien
Cheng-Lee Lai(賴振立)
Tsai, Hui-An
Hung, Wei-Song
Hu, Chien-Chieh
Chang, Yung
Lee, Kueir-Rarn |
| 貢獻者: | Chung Yuan Christian Univ, Dept Chem Engn, R&D Ctr Membrane Technol
Mapua Univ, Sch Chem Biol & Mat Engn & Sci
Sichuan Univ Sci & Engn, Mat Corros & Protect Key Lab Sichuan Prov, Coll Mat Sci & Engn
Natl Ilan Univ, Dept Chem & Mat Engn
Chia Nan Univ Pharm & Sci, Dept Environm Engn & Sci
Natl Taiwan Univ Sci & Technol, Grad Inst Appl Sci & Technol |
| 關鍵字: | Graphene oxide
Pervaporation
Zwitterion
Pressure-assisted filtration |
| 日期: | 2019-10 |
| 上傳時間: | 2020-07-29 13:51:08 (UTC+8) |
| 出版者: | ELSEVIER SCIENCE BV |
| 摘要: | Zwitterionic copolymers, poly(glycidyl methacrylate-sulfobetaine methacrylate) [poly(GMA-SBMA)], was incorporated into graphene oxide (GO) to form a GO-poly(GMA-SBMA) framework. This compound was then deposited onto a polysulfone support through pressure-assisted filtration to fabricate hybrid membranes. Optimum fabrication conditions were determined by varying the poly(GMA-SBMA) loading. Attenuated total reflectance-Fourier transform infrared and X-ray photoelectron spectroscopy confirmed the covalent bonding between poly(GMA-SBMA) and GO. On account of loading incremental amounts of poly(GMA-SBMA), the membrane thickness was increased (illustrated by field emission scanning electron microscopic images), the interlayer spacing between GO sheets was expanded (shown by X-ray diffraction patterns), and the membrane hydrophilic properties were enhanced (indicated by water contact angle data). Relative to the pristine GO membrane, hybrid membranes fabricated at optimum conditions exhibited superior separation performance (99.60 wt% water concentration in permeate and 1102 gm(-2).h(-1) permeation flux) on dehydrating a 70 wt% aqueous isopropanol solution by pervaporation. This present study explored the potential of poly(GMA-SBMA) for developing hybrid membranes with excellent pervaporation performance. |
| 關聯: | Journal of Membrane Science, v.587, UNSP 117188 |
| 顯示於類別: | [環境工程與科學系(所)] 期刊論文
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