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    Please use this identifier to cite or link to this item: http://ir.cnu.edu.tw/handle/310902800/32582


    標題: Removal of zinc based on a screw manufacturing plant wastewater by fluidized-bed homogeneous granulation process
    作者: Udomkitthaweewat, Nutnapong
    Anotai, Jin
    Choi, Angelo Earvin Sy
    Lu, Ming Chun
    貢獻者: Chia Nan Univ Pharm & Sci, Dept Environm Resources Management
    King Mongkuts Univ Technol Thonburi, Dept Environm Engn, Fac Engn
    King Mongkuts Univ Technol Thonburi, Dept Environm Engn, Ctr Excellence Hazardous Subst Management
    Natl Res Ctr Disaster Free & Safe Ocean City
    關鍵字: Fluidized-bed homogeneous granulation process
    Hydrozincite
    Nucleation
    Ferric ions
    Chloride
    Zinc crystallization
    日期: 2019-09
    上傳時間: 2020-07-29 13:50:47 (UTC+8)
    出版者: ELSEVIER SCI LTD
    摘要: Wastewater derived from screw producing manufacturing plants contains high zinc concentrations that needs to be treated prior to its discharge. Crystallization through the fluidized-bed reactor has been an effective technology for the removal of heavy metals. In this research, the removal of zinc from a simulated wastewater was investigated by a fluidized-bed reactor. The properties of the granules were characterized by utilizing the X-ray diffraction, energy dispersive spectrometer and scanning electron microscope. A comparison of the fluidized-bed reactor setting was conducted to compare the processes of fluidized-bed homogeneous granulation and fluidized-bed granulation. Results showed that the fluidized-bed homogeneous granulation outperformed fluidized-bed granulation in terms of removal and granulation efficiencies. The essential variables for analysis include chloride concentration (0-7,000 mg/L), pH (6.9-7.5), carbonate to zinc molar ratio (1-2.5) and ferric ion concentration (0-150 mg/L) in the fluidized-bed homogeneous granulation process. The results indicated that the ideal conditions for hydrozincite granulation were at a carbonate to zinc molar ratio of 1.2 and pH 7.2. The elemental composition analysis of the hydrozincite revealed zinc contents of the following: (1) absence of chloride (63.71 wt% zinc), (2) presence of chloride (63.08 wt% zinc) and (3) presence of ferric ions (52.62 wt% zinc). The inclusion of chloride and ferric ions in the system interfered with zinc precipitation and granulation. Furthermore, the hydrozincite granule predominantly reached a diameter of 149 mu m (with chloride) and 42 mu m (with ferric ions). (C) 2019 Elsevier Ltd. All rights reserved.
    關聯: Journal of Cleaner Production, v.230, p.1276-1286
    Appears in Collections:[環境資源管理系(所)] 期刊論文

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