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    Please use this identifier to cite or link to this item: http://ir.cnu.edu.tw/handle/310902800/30908

    標題: Thermoresponsive Conductive Polymer Composite Thin Film and Fiber Mat: Crosslinked PEDOT:PSS and P(NIPAAm-co-NMA) Composite
    作者: Huang, Shih-Ru
    Lin, King-Fu
    Don, Trong-Ming
    Lee, Chai-Fen
    Wang, Man-Sheng
    Chiu, Wen-Yen
    貢獻者: Natl Taiwan Univ, Inst Polymer Sci & Engn
    Natl Taiwan Univ, Dept Mat Sci & Engn
    Tamkang Univ, Dept Chem & Mat Engn
    Chia Nan Univ Pharm & Sci, Dept Cosmet Sci
    Natl Taipei Univ Technol, Dept Chem Engn & Biotechnol
    Natl Taiwan Univ, Dept Chem Engn
    關鍵字: composite
    conductive polymer
    日期: 2016-04
    上傳時間: 2018-01-18 11:37:42 (UTC+8)
    出版者: Wiley-Blackwell
    摘要: The thermoresponsive conductive composite (TCC) thin films and fiber mats, whose electrical property changed with temperature, were fabricated successfully. The thermocrosslinkable and thermoresponsive copolymer, poly (N-isopropyl acrylamide-co-N-methylolacrylamide) (PNN), was synthesized. The TCC thin film and fiber mat were fabricated by spin coating and electrospinning process of PEDOT:PSS/PNN solutions, respectively. After thermocrosslinking and doping by DMSO, the composite thin films and fiber mats were obtained. Fibrous structures of TCC fiber mats were observed by SEM. The surface resistance and conductivity of composites were measured. The thermoresponsivity and swelling ratio of TCCs were also studied. The thermoresponsive conductive property was analyzed by measuring the surface resistance of TCCs in water bath under various temperatures from 20 to 50 degrees C. With the increase of temperature, the TCCs shrank to be dense structure and showed lower surface resistance. The TCC fibers mat exhibited greater sensitivity to temperature than thin film owing to its fibrous structure. (C) 2015 Wiley Periodicals, Inc.
    關聯: Journal of Polymer Science Part A-Polymer Chemistry, v.54 n.8, pp.1078-1087
    Appears in Collections:[化妝品應用與管理系(所)] 期刊論文

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