Chia Nan University of Pharmacy & Science Institutional Repository:Item 310902800/30487
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    標題: Palladium-catalyzed 1,2-addition of organic halide and terminal alkyne to 7-oxabenzonorbornadiene;an efficient route to polyaromatic
    作者: Chun-Jung Kuo(郭俊榕)
    Shu-jin Cheng(鄭淑瑾)
    Shu-Ting Chang(張淑婷)
    Charng-Hsing Liu(劉常興)
    貢獻者: Department of Applied Chemistry, Chia Nan University of Pharmacy and Science
    關鍵字: three-component coupling reaction
    palladium-catalyzed
    7-oxabenzonorbornadiene
    terminal alkyne
    日期: 2008-07
    上傳時間: 2017-12-04 15:54:36 (UTC+8)
    摘要: A three-component coupling reaction of organic halides with oxabicyclic alkene and terminal alkynes was catalyzed by a palladium complex and phase transfer agent in the presence of aqueous NaOH. The reaction gave a series of 5,6-disubstituated 7-oxabenzonorbornene derivatives in good yields . The disubstituted products from oxabenzonorbornadiene can be readily converted to polyaromatic hydrocarbons via a Lewis acid mediated deoxyaromatization reaction.
    關聯: 第五屆海峽化學、生物及材料研討會,起迄日:2008/07/21-2008/07/22,地點:嘉南藥理科技大學
    顯示於類別:[食藥產業暨檢測科技系(含五專)] 會議論文
    [藥理學院] 2008第五屆海峽化學、生物及材料研討會

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