| 標題: | Palladium-catalyzed 1,2-addition of organic halide and terminal alkyne to 7-oxabenzonorbornadiene;an efficient route to polyaromatic |
| 作者: | Chun-Jung Kuo(郭俊榕)
Shu-jin Cheng(鄭淑瑾)
Shu-Ting Chang(張淑婷)
Charng-Hsing Liu(劉常興) |
| 貢獻者: | Department of Applied Chemistry, Chia Nan University of Pharmacy and Science |
| 關鍵字: | three-component coupling reaction
palladium-catalyzed
7-oxabenzonorbornadiene
terminal alkyne |
| 日期: | 2008-07 |
| 上傳時間: | 2017-12-04 15:54:36 (UTC+8) |
| 摘要: | A three-component coupling reaction of organic halides with oxabicyclic alkene and terminal alkynes was catalyzed by a palladium complex and phase transfer agent in the presence of aqueous NaOH. The reaction gave a series of 5,6-disubstituated 7-oxabenzonorbornene derivatives in good yields . The disubstituted products from oxabenzonorbornadiene can be readily converted to polyaromatic hydrocarbons via a Lewis acid mediated deoxyaromatization reaction. |
| 關聯: | 第五屆海峽化學、生物及材料研討會，起迄日：2008/07/21-2008/07/22，地點：嘉南藥理科技大學 |
| 顯示於類別: | [食藥產業暨檢測科技系(含五專)] 會議論文
[藥理學院] 2008第五屆海峽化學、生物及材料研討會
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