Electrochemical Oxidation of Fragrances 4-Allyl and 4-Propenylbenzenes on Platinum and Carbon Paste Electrodes

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Title:	Electrochemical Oxidation of Fragrances 4-Allyl and 4-Propenylbenzenes on Platinum and Carbon Paste Electrodes
Authors:	Wang, Lai-Hao Chang, Chia-Ling Hu, Yi-Chun
Contributors:	醫藥化學系
Keywords:	electrochemical oxidation 4-allylbenzenes 4-propenylbenzenes
Date:	2015-03
Issue Date:	2016-04-19 19:01:47 (UTC+8)
Publisher:	Croatian Chemical Soc
Abstract:	The electrochemical oxidation behaviors of 4-allylbenzenes (estragole, safrole and eugenol) and 4-propenylbenzenes (anethole, asarone and isoeugenol) on platinum and carbon paste electrodes were investigated in a Britton-Robinson buffer (pH = 2.93 and 10.93), acetate buffer, phosphate buffer solutions (pH = 2.19 and 6.67), and acetonitrile containing various supporting electrolytes examined lithium perchlorate. Their oxidation potential with Hammett (free-energy relationships) and possible reaction mechanisms were discussed.
Relation:	Croatica Chemica Acta, v.88 n.1, pp.35-42
Appears in Collections:	[Dept. of Food & Drug Industry and Inspective Technology] Periodical Articles

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