Polychlorinated Dibenzo-p-dioxin and Dibenzofuran (PCDD/F) Emission Behavior during Incineration of Laboratory Wastes. Part 2: PCDD/F Profiles and Characteristics of Output Materials

doi:10.4209/aaqr.2013.05.0141

CNU IR > College of Sustainable Environment and Recreation > Dept. of Environmental Resources Management > Periodical Articles > Item 310902800/28648

Please use this identifier to cite or link to this item: https://ir.cnu.edu.tw/handle/310902800/28648

Title:	Polychlorinated Dibenzo-p-dioxin and Dibenzofuran (PCDD/F) Emission Behavior during Incineration of Laboratory Wastes. Part 2: PCDD/F Profiles and Characteristics of Output Materials
Authors:	Liao, Wei-Tung Wang, Ya-Fen Tsai, Cheng-Hsien Tsai, Ying-I Wu, Zhong-Lin Kuo, Yi-Ming
Contributors:	環境資源管理系
Keywords:	Fly ash Cl Crystalline phase Quenching tower
Date:	2014-06
Issue Date:	2015-05-06 21:23:47 (UTC+8)
Publisher:	Taiwan Assoc Aerosol Res-Taar
Abstract:	This study investigates the polychlorinated dibenzo-p-dioxin and dibenzofuran (PCDD/F) profiles of output materials and the influence of Cl content of input materials during the incineration of laboratory waste. The specimens, namely bottom ash (BTA), first quenching tower ash (FQA), secondary quenching tower ash (SQA), baghouse ash (BHA), and stack flue gas (SFG), were sampled and analyzed using high-resolution gas chromatography/high-resolution mass spectrometry, field-emission scanning electron microscopy (FE-SEM), ion chromatography, and X-ray diffraction (XRD). The Cl content was highest in FQA, followed by that in SQA, BHA, and BTA, and most of the Cl existed in soluble form, especially for FQA and SQA. The Cl mass was mainly distributed in FQA and BTA during incineration. The PCDD/F content of ash in each category was highly related to the Cl level in the input materials. The PCDD/Fs of all ashes and the particulate phase of SFG were mainly 7-Cl or 8-Cl PCDD/Fs, but those of the gas phase in SFG were mainly 4-6 Cl PCDD/Fs. In addition, an increase of Cl in the input materials increased the fractions of 7-Cl and 8-Cl PCDD/Fs. The XRD analysis results indicate that the main crystalline phase in fly ashes was NaCl. FE-SEM images show a porous granular morphology, which is consistent with the XRD analysis results.
Relation:	Aerosol and Air Quality Research, v.14 n.4, pp.1206-1214
Appears in Collections:	[Dept. of Environmental Resources Management] Periodical Articles

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