Optimization of ultrasound-assisted oxidative desulfurization of model sulfur compounds using commercial ferrate (VI)

doi:10.1016/j.jtice.2014.08.003

CNU IR > College of Sustainable Environment and Recreation > Dept. of Environmental Engineering and Science (including master's program) > Periodical Articles > Item 310902800/28637

jsp.display-item.identifier=請使用永久網址來引用或連結此文件: https://ir.cnu.edu.tw/handle/310902800/28637

题名:	Optimization of ultrasound-assisted oxidative desulfurization of model sulfur compounds using commercial ferrate (VI)
作者:	Choi, Angelo Earvin Sy Roces, Susan Dugos, Nathaniel Futalan, Cybelle Morales Lin, Shiow-Shyung Wan, Meng-Wei
贡献者:	環境工程與科學系
关键词:	Benzothiophene Box-Behnken Design Dibenzothiophene Ferrate Ultrasound-assisted oxidative desulfurization
日期:	2014-11
上传时间:	2015-05-06 21:23:24 (UTC+8)
出版者:	Elsevier Science Bv
摘要:	In this study, ultrasound-assisted oxidative desulfurization of benzothiophene and dibenzothiophene using ferrate and a phase transfer agent was investigated. The effects of ferrate concentration (100-300 ppm), phase transfer agent (100-300 mg), ultrasonication time (10-30 min), and organic to aqueous phase ratio (10:30-30:10) on sulfur reduction were examined. A Box-Behnken design was utilized to evaluate the effects of various parameters and determine optimum conditions in desulfurization. The level of significance of each parameter and their interaction were analyzed using the analysis of variance. Results showed the optimal conditions for benzothiophene to be 16.4 min, 122.1 mg PTA, 29.7 mL:10.3 mL and 204.8 ppm ferrate. Meanwhile, optimum desulfurization conditions for dibenzothiophene could be attained at 29.5 min, 111.6 mg PTA, 16.2 mL:23.8 mL and 245.3 ppm ferrate. Moreover, sulfur removal of 85.7% and 91.0% in diesel oil was achieved for benzothiophene and dibenzothiophene using the optimized conditions. (C) 2014 Taiwan Institute of Chemical Engineers. Published by Elsevier B.V. All rights reserved.
關聯:	Journal of the Taiwan Institute of Chemical Engineers, v.45 n.6, pp.2935-2942
显示于类别:	[Dept. of Environmental Engineering and Science (including master's program)] Periodical Articles

文件中的档案:

档案	描述	大小	格式	浏览次数
index.html		0Kb	HTML	2149	检视/开启

在CNU IR中所有的数据项都受到原著作权保护.

TAIR相关文章

数据加载中.....