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    Please use this identifier to cite or link to this item: http://ir.cnu.edu.tw/handle/310902800/27941


    標題: The comparative electrochemistry of 2-mercaptothiazoline when using gold/quartz and modified silver/quartz electrodes, and its application in a flow-through voltammetric sensor
    作者: Wang, Lai-Hao
    Chang, Yu-Hsuan
    貢獻者: 醫藥化學系
    關鍵字: Thioureido Type Compounds
    Acidic Aqueous-Solution
    Mercury(Ii) Ion
    Corrosion
    Layer
    Steel
    Derivatives
    Adsorption
    Inhibitors
    Monolayer
    日期: 2013
    上傳時間: 2014-05-26 10:49:55 (UTC+8)
    出版者: Royal Soc Chemistry
    摘要: We studied the electrochemical behavior of 2-mercaptothiazoline (1,3-thiazolidine-2-thione) on silver (Ag)/quartz and gold (Au)/quartz electrodes electrochemically deposited it on silver metal film on Ag/quartz substrates, and investigated it using electrochemical quartz crystal microbalance (EQCM) analysis with AT-cut quartz crystals (9 MHz). We found that the electrocatalytic property of Ag/quartz was better than that of gold/quartz. In addition, 2-mercaptothiazoline was detected using high-performance liquid chromatography with an electrochemical (Ag) detector (HPLC-ECD). For direct current mode, with the current at a constant potential, and measurements with suitable experimental parameters, we found a linear concentration range from 0.01 to 0.80 mu g mL(-1). The lower limit of detection using our method was approximately 0.1 ng. Findings using HPLC-ECD and HPLC with an ultraviolet detector were comparable.
    關聯: Analytical Methods, v.5 n.6 pp.1407-1413
    Appears in Collections:[醫藥化學系 ] 期刊論文

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