Synthesis and characteristics of poly(N-isopropylacrylamide-co-methacrylic acid)/Fe3O4/poly(N-isopropylacrylamide-co-methacrylic acid) two-shell thermosensitive magnetic composite hollow latex particles

doi:10.1002/pola.26680

Chia Nan University of Pharmacy & Science Institutional Repository > 藥理學院 > 化妝品應用與管理系(所) > 期刊論文 > Item 310902800/27936

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標題:	Synthesis and characteristics of poly(N-isopropylacrylamide-co-methacrylic acid)/Fe3O4/poly(N-isopropylacrylamide-co-methacrylic acid) two-shell thermosensitive magnetic composite hollow latex particles
作者:	Lee, Chia-Fen Wang, Yu-Cheng Chiu, Wen-Yen
貢獻者:	化妝品應用與管理系
關鍵字:	Core-Shell Polymers Emulsion Polymerization Fe3O4 Hollow Latex Particle Morphology Soapless Emulsion Polymerization Thermosensitivity Vptt
日期:	2013-07
上傳時間:	2014-05-26 10:49:43 (UTC+8)
出版者:	Wiley-Blackwell
摘要:	In this study, the poly(N-isopropylacrylamide-methylacrylate acid)/Fe3O4/poly(N-isopropylacrylamide-methylacrylate acid) (poly(NIPAAm-MAA)/Fe3O4/poly(NIPAAm-MAA)) two-shell magnetic composite hollow latex particles were synthesized by four steps. The poly(methyl methacrylate-co-methylacrylate acid) (poly(MMA-MAA)) copolymer latex particles were synthesized first. Then, the second step was to polymerize NIPAAm, MAA, and crosslinking agent in the presence of poly(MMA-MAA) latex particles to form the linear poly(MMA-MAA)/crosslinking poly(NIPAAm-MAA) core-shell latex particles. Then, the core-shell latex particles were heated in the presence of NH4OH to dissolve the linear poly(MMA-MAA) core to form the poly(NIPAAm-MAA) hollow latex particles. In the third step, the Fe3O4 nanoparticles were generated in the presence of poly(NIPAAm-MAA) hollow polymer latex particles and formed the poly(NIPAAm-MAA)/Fe3O4 magnetic composite hollow latex particles. The fourth step was to synthesize poly(NIPAAm-MAA) in the presence of poly(NIPAAm-MAA)/Fe3O4 latex particles to form the poly(NIPAAm-MAA)/Fe3O4/poly(NIPAAm-MAA) two-shell magnetic composite hollow latex particles. The effect of various variables such as reactant concentration, monomer ratio, and pH value on the morphology and volume-phase transition temperature of two-shell magnetic composite hollow latex particles was studied. Moreover, the latex particles were used as carriers to load with caffeine, and the caffeine-loading characteristics and caffeine release rate of latex particles were also studied. (c) 2013 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2013, 51, 2880-2891
關聯:	Journal of Polymer Science Part A-Polymer Chemistry, v.51 n.13, pp.2880-2891
顯示於類別:	[化妝品應用與管理系(所)] 期刊論文

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