Chia Nan University of Pharmacy & Science Institutional Repository:Item 310902800/27887
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    题名: Metal-Silver Based Electrodes as Sensitive Surfaces for Electrochemical Detection of Thio-Heterocycles
    作者: Wang, Lai-Hao
    Lin, Yung-Hua
    贡献者: 醫藥化學系
    关键词: Metal Films On Ag/Quartz Crystal
    Electrochemical Quartz Crystal Microbalance
    Thio-Heterocycle
    日期: 2013-09
    上传时间: 2014-05-26 10:47:42 (UTC+8)
    出版者: IEEE-Inst Electrical Electronics Engineers Inc
    摘要: The electrodeposition of various metal films [lead (Pb), zinc (Zn), cadmium (Cd), copper (Cu), antimony (Sb), nickel (Ni), and tin (Sn)] onto silver (Ag)/quartz crystal substrate is studied using a electrochemical quartz crystal microbalance. The surface morphologies and crystal nanostructures of the dendrites are characterized by a scanning electron microscope (SEM) and energy dispersive X-ray spectroscopy. The composite of the modified bimetallic alloy electrode is characterized by electrochemical impedance spectroscopy and cyclic voltammatry. SEM images show particle sizes ranging from 73 to 280 nm with an average of 215 nm of metal films on the Ag/quartz electrodes. The modified metal Ag/quartz alloy electrodes are used to determine the thio-heterocycle in various supporting electrolytes. We found the electrocatalytic property of zinc is better than that of the other metals and un-coated Ag/quartz.
    關聯: IEEE Sensors Journal, v.13 n.9, pp.3442-3448
    显示于类别:[Dept. of Food & Drug Industry and Inspective Technology] Periodical Articles

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