Loading...
|
Please use this identifier to cite or link to this item:
https://ir.cnu.edu.tw/handle/310902800/27008
|
| Title: | Kinetics of 2,6-Dimethylaniline Oxidation by Various Fenton Processes |
| Authors: | Masomboon, Nalinrut
Ratanatamskul, Chavalit
Lu, Ming-Chun |
| Contributors: | 環境資源管理系 |
| Keywords: | 2,6-Dimethylaniline
Kinetics
Fenton process
Electro-Fenton process
Photoelectro-Fenton process |
| Date: | 2011-08 |
| Issue Date: | 2013-10-16 16:57:24 (UTC+8) |
| Publisher: | Elsevier |
| Abstract: | The kinetics of 2,6-dimethylaniline degradation by Fenton process, electro-Fenton process and photoelectro-Fenton process was investigated. This study attempted to eliminate the potential interferences from intermediates by making a kinetics comparison of Fenton, electro-Fenton and photoelectro-Fenton methods through use initial rate techniques during the first 10 min of the reaction. Exactly how the initial concentration of 2,6-dimethylaniline, ferrous ions and hydrogen peroxide affects 2,6-dimethylaniline degradation was also examined. Experimental results indicate that the 2,6-dimethylaniline degradation in the photoelectro-Fenton process is superior to the ordinary Fenton and electro-Fenton processes. Additionally, for 100% removal of 1 mM 2,6-dimethylaniline, the supplementation of 1 mM of ferrous ion, 20 mM of hydrogen peroxide, current density at 15.89 A m−2 and 12 UVA lamps at pH 2 was necessary. The overall rate equations for 2,6-dimethylaniline degradation by Fenton, electro-Fenton and photoelectro-Fenton processes were proposed as well. |
| Relation: | Journal of Hazardous Materials, 192(1), pp.347-353 |
| Appears in Collections: | [Dept. of Environmental Resources Management] Periodical Articles
|
Files in This Item:
| File |
Description |
Size | Format | |
|---|
| index.html | | 0Kb | HTML | 2127 | View/Open |
|
All items in CNU IR are protected by copyright, with all rights reserved.
|
