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    標題: Comparison of Aniline Oxidation by Electro-Fentonand Fluidized-Bed Fenton Processes
    作者: Anotai, Jin
    Su, Chia-Chi
    Tsai, Yi-Chun
    Lu, Ming-Chun
    貢獻者: 環境資源管理系
    關鍵字: Electro-Fenton process
    Fluidized-bed Fenton process
    Hydrogen peroxide
    Aniline
    Inorganic ions
    日期: 2011-05
    上傳時間: 2013-10-16 16:57:12 (UTC+8)
    出版者: ASCE-AMER SOC CIVIL ENGINEERS
    摘要: This study investigated the aniline oxidation at various conditions, namely, pH, H(2)O(2) dose, Fe(2+) dose, and aniline concentration, as well as the effects of inorganic ion concentrations on the electro-Fenton and fluidized-bed Fenton processes. Aniline degradation depended on the H(2)O(2) and Fe(2+) dose for both processes. The results showed that both processes had the best aniline oxidation efficiency at pH 2.8-3.2. In the electro-Fenton process, approximately 95% of the aniline was removed after 60 min. While the SiO(2) carrier contents of fluidized-bed Fenton process was adjusted to 74 g/L, the aniline was gradually removed, and the degradation rate finally reached 83%. The inhibition effect of phosphate ions on aniline oxidation on both processes was more significant than that of chloride ions. Chloride ions have higher inhibition ability on aniline oxidation in the fluidized-bed Fenton process than in the electro-Fenton process. However, the inhibition of phosphate ions on aniline oxidation in the electro-Fenton process was more obvious than in the fluidized-bed Fenton process. DOI: 10.1061/(ASCE)EE.1943-7870.0000325. (C) 2011 American Society of Civil Engineers.
    關聯: JOURNAL OF ENVIRONMENTAL ENGINEERING, 137(5), pp.363-370
    顯示於類別:[環境資源管理系(所)] 期刊論文

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