Preparation of thermally curable conductive films PEDOT:P(SS-NMA) and their

doi:10.1016/j.polymer.2011.08.044

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標題:	Preparation of thermally curable conductive films PEDOT:P(SS-NMA) and their
作者:	Yin, Hui-En Lee, Chia-Fen Chiu, Wen-Yen
貢獻者:	化粧品應用與管理系
關鍵字:	Thermally curable conductive film PEDOT:PSS Weather stability and water resistance
日期:	2011-10
上傳時間:	2013-06-03 15:52:59 (UTC+8)
出版者:	Elsevier
摘要:	In this research, sodium 4-styrenesulfonate (SSNa) and N-(methylol acrylamide) (NMA) were copolymerized to form the thermally curable copolymer P(SS-NMA). Moisture absorptivity and swelling index were used to evaluate the weather stability of P(SS-NMA). The P(SS-NMA) copolymers with high molar content of NMA exhibited better weather stability. Then, P(SS-NMA) was used as the polymeric template to carry out the oxidative polymerization of 3,4-ethylenedioxythiophene (EDOT) and yielded the thermally curable conductive dispersion, poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate-N-(methylol acrylamide)) (PEDOT:P(SS-NMA)). The optoelectronic property and surface morphology for the PEDOT:P(SS-NMA) conductive thin films were investigated. In addition, the performance of the PEDOT:P(SS-NMA) conductive film was characterized in the two parts: weather stability and water resistance. The introduction of crosslinking structures into the conductive film improved the mechanical property and weather stability so as to resolve the drawbacks of the commercial products PEDOT:PSS.
關聯:	Poymer 52(22), pp. 5065-5074
顯示於類別:	[化妝品應用與管理系(所)] 期刊論文

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