以Amine-s-triazine-C18 鍵結靜相在HPLC上分離多環芳香烴

CNU IR > Chna Nan Annual Bulletin > No.37 (2011) > Item 310902800/25473

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Title:	以Amine-s-triazine-C18 鍵結靜相在HPLC上分離多環芳香烴 Use of Amine-s-triazine-C18 Bonded Phase for the Separation of Polycyclic Aromatic Hydrocarbons by HPLC
Authors:	廖麗芳楊朝成張書文吳忠誠林振興
Contributors:	輔英科技大學應用化學及材料科學系嘉南藥理科技大學化粧品科技研究所
Keywords:	高效液相層析多環芳香烴 s-三口井環 High-PerformanceLiquidChromatography PolycyclicAromaticHydrocarbons s-Triazine
Date:	2011-12
Issue Date:	2012-06-08 15:10:04 (UTC+8)
Abstract:	本研究製備amine-s-triazine-C18 鍵結靜相的目的，在於分離多環芳香烴。以amine-s-triazine-C18 鍵結靜相在HPLC 上，對一些多環芳香烴的分離及滯留行為的探討。在移動相中，乙腈與水比例為55:45 時，可以有效分離7 種多環芳香烴。由層析結果顯示，鍵結靜相與分析物之間的疏水性作用力以及π-π 作用力，在滯留機轉上，扮演重要的角色。 The amine-s-triazine-C18 bonded phase was prepared for the separation of polycyclic aromatic hydrocarbons. The separation and retention behavior of seven polycyclic aromatic hydrocarbons was investigated in HPLC using Amine-s-triazine-C18 bonded phase. Effective separations of the seven polycyclic aromatic hydrocarbons were achieved using acetonitrile-water (55:45, v/v) in mobile phase. Chromatographic results indicate that π-π interaction and hydrophobic interaction between the bonded phase and analytes play significant roles in the retention mechanism.
Relation:	嘉南學報(科技類) 37期：p.8-13
Appears in Collections:	[Chna Nan Annual Bulletin] No.37 (2011) [Dept. of Cosmetic Science and institute of cosmetic science] Periodical Articles

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