Oxidation of 2,6-dimethylaniline by the fluidized-bed Fenton process

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標題:	Oxidation of 2,6-dimethylaniline by the fluidized-bed Fenton process
作者:	Chavalit Ratanatamskul Sutthinee Narkwittaya Nalinrut Masomboon Ming-Chun Lu
貢獻者:	環境資源管理系
關鍵字:	2,6-Dimethylaniline Fluidized-bed Fenton process Hydroxyl radicals Crystallization
日期:	2010-11
上傳時間:	2012-05-31 14:49:42 (UTC+8)
摘要:	,6-Dimethylaniline was oxidized using the fluidized-bed Fenton process. This study examined the effects of pH, ferrous ion, hydrogen peroxide and 2,6-dimethylaniline concentrations. Results showed that the optimum pH for removing 2,6-dimethylaniline was 3. Ferrous ion and hydrogen peroxide concentrations were the important parameters in 2,6-dimethylaniline degradation. Increasing ferrous ion and hydrogen peroxide concentrations can enhance the degradation efficiency of 2,6-dimethylaniline. However, excess amounts of ferrous ions and hydrogen peroxide can cause scavenging effects in the reaction, thus decreasing the 2,6-dimethylaniline removal efficiency. The optimum concentrations of ferrous ion and hydrogen peroxide for degrading 1 mM of 2,6-dimethylaniline were 2.5 mM and 10 mM, respectively. In addition, the fluidized-bed Fenton process was proven to have higher degradation ability than the conventional Fenton process.
關聯:	Reaction Kinetics, Mechanism and Catalysis 101(2)：p.301-311
顯示於類別:	[環境資源管理系(所)] 期刊論文

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