Dissociation Kinetics of Aqua[(1SR, 4RS, 7RS, 8SR, 11RS, 14RS)-5,5,7,12,12,14'-Hexamethyl-1,4,8,11-Tetraazacyclotetradcane]Copper(Ⅱ) (Red) Cation in Strongly Acidic, Aqueous Media

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Title:	Dissociation Kinetics of Aqua[(1SR, 4RS, 7RS, 8SR, 11RS, 14RS)-5,5,7,12,12,14'-Hexamethyl-1,4,8,11-Tetraazacyclotetradcane]Copper(Ⅱ) (Red) Cation in Strongly Acidic, Aqueous Media
Authors:	Lien-Huei Chen Chung-Sun Chung
Contributors:	應用化學科
Keywords:	Kinetics of [Cu(tet b)(H2O)(red)]2+
Date:	1989
Issue Date:	2011-09-14 15:37:38 (UTC+8)
Abstract:	In order to investigate the effect of structure variation upon complex dissociation rate constants, the kinetics of the dissociation of (C-rac-5,5,7,12,12,14-hexamethyl-1,4,811-tetraazacyclotetradecane) copper(II) (red) cation has been examined spectrophotometrically at 25.0℃ in 0.1-5.0 M HNO3. The possible pathways for the cleavages of the copper-nitrogen bonds, the factors influencing the dissociation rates, and the factors affecting the relative importance of each of these possible pathways are considered.
Relation:	嘉南學報 15 : p.A7-A15 轉載 Journal of the Chinese Chemical Society 36(3),p.195-203 (1989)
Appears in Collections:	[Chna Nan Annual Bulletin] Vol.15 (1989) [Dept. of Food & Drug Industry and Inspective Technology] Periodical Articles

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