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    Please use this identifier to cite or link to this item: http://ir.cnu.edu.tw/handle/310902800/23263

    標題: Hierarchical kinetic simulation for autocatalytic decomposition of cumene hydroperoxide at low temperatures
    作者: Jiann-Rong Chen
    Shyh-Yuch Cheng
    Min-Hao Yuan
    Arcady A. Kossoy
    Chi-Min Shu
    貢獻者: 職業安全衛生系
    關鍵字: Autocatalytic decomposition
    Best-fit approach
    Cumene hydroperoxide (CHP)
    Kinetic parameters
    Meticulous multi-stage model
    日期: 2009-06
    上傳時間: 2010-11-19 11:50:17 (UTC+8)
    摘要: A hierarchical set of kinetic models were proposed and discussed for simulation of autocatalytic decomposition of cumene hydroperoxide (CHP) in cumene at low temperatures. The hierarchy leads from a formal model of full autocatalysis, which is based on conversion degree as a state variable, through a two-stage autocatalytic concentration-based model to a meticulous multi-stage model of the reaction. By the ForK (Formal Kinetics) and DesK (Descriptive Kinetics) software, developed by ChemInform Saint Petersburg (CISP) Ltd., the related kinetic parameters and their significance have also been estimated and elucidated. Through this best-fit approach, it is possible to formulate a systematic methodology on the kinetic studies for thermal decomposition of typical organic peroxides with autocatalytic nature, specifically at low temperature ranges.
    關聯: Journal of Thermal Analysis and Calorimetry 96(3):p.751-758
    Appears in Collections:[職業安全衛生系(含防災所)] 期刊論文

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