Runaway Reaction on tert-Butyl Peroxybenzoate by DSC Tests

doi:10.1007/s10973-007-8831-z

CNU IR > College of Sustainable Environment and Recreation > Dept. of Occupational Safety > Periodical Articles > Item 310902800/21701

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題名:	Runaway Reaction on tert-Butyl Peroxybenzoate by DSC Tests
作者:	Shyh-Yueh Cheng Jo-Ming Tseng Sheng-Yi Lin Jai P. Gupta Chi-Min Shu
貢獻者:	職業安全衛生系
關鍵詞:	tert–butyl peroxybenzoate (TBPB) runaway reactions differential scanning calorimetry (DSC) kinetic parameters curve–fitting method
日期:	2008-07
上傳時間:	2009-10-07 16:53:32 (UTC+8)
摘要:	Tert–butyl peroxybenzoate (TBPB) is one of the sensitive and hazardous chemicals which have been popularly employed in petrifaction industries in the past. This study attempted to elucidate its unsafe characteristics and thermally sensitive structure so as to help prevent runaway reactions, fires or explosions in the process environment. We employed differential scanning calorimetry (DSC) to assess the kinetic parameters (such as exothermic onset temperature (T0), heat of reaction (ΔH), frequency factor (A)), and the other safety parameters using four different scanning rates (1, 2, 4, and 10℃ min–1) combined with curve–fitting method. The results indicated that TBPB becomes very dangerous during decomposition reactions; the onset temperature and reaction heat were about 100℃ and 1,300 J g–1, respectively. Through this study, TBPB accidents could be reduced to an accepted level with safety parameters under control. According to the findings in the study and the concept of inherent safety, TBPB runaway reactions could be thoroughly prevented in the relevant plants.
關聯:	Journal of Thermal Analysis and Calorimetry 93(1)：p.121-126
顯示於類別:	[Dept. of Occupational Safety] Periodical Articles

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