1-乙烯咪唑在室溫離子液體中之反向原子轉移自由基聚合

CNU IR > Chna Nan Annual Bulletin > No.33 (2007) > Item 310902800/19065

Please use this identifier to cite or link to this item: https://ir.cnu.edu.tw/handle/310902800/19065

Title:	1-乙烯咪唑在室溫離子液體中之反向原子轉移自由基聚合 Reverse Atom Transfer Radical Polymerization of 1-Vinylimidazole in Room Temperature Ionic Liquids
Authors:	何文岳劉家全呂昆霖楊彩秀魏騰芳劉瑞珍許智偉
Contributors:	化粧品應用與管理系化粧品科技研究所保健營養系營養與保健科技研究所
Keywords:	離子液體反向原子轉移自由基聚合 1-甲基咪唑 1-乙烯咪唑 Ionic liquid Reverse atom transfer radical polymerization 1-Methylimidazole 1-Vinylimidazole
Date:	2007
Issue Date:	2009-04-12 09:56:10 (UTC+8)
Abstract:	本研究利用室溫離子液體為溶劑，以1-乙烯咪唑為反應單體進行反向原子轉移自由基聚合反應之研究。在室溫離子液體的合成上，以1-甲基咪唑為原料，經由烷基化與陰離子交換反應後，製備出5種室溫離子液體。接著以此室溫離子液體為溶劑，利用氯化銅(II)為催化劑進行1-乙烯咪唑單體的反向原子轉移自由基聚合反應研究，由反應之結果顯示：聚合物分子量之分布範圍主要受到離子液體黏度的影響，而相同陰離子結構的離子液體其黏度越低，則反應後聚合物分子量之分布會越狹窄。 This research was about reverse atom transfer radical polymerization of 1-vinylimidazole in room temperature ionic liquids. Five room temperature ionic liquids were synthesized by using 1-methylimidazole as starting material, and CuCl2 was selected as cat
Relation:	嘉南學報(科技類) 33期：p.89-95
Appears in Collections:	[Chna Nan Annual Bulletin] No.33 (2007) [Dept. of Cosmetic Science and institute of cosmetic science] Periodical Articles [Dept. of Health and Nutrition (including master's program)] Periodical Articles

Files in This Item:

File	Description	Size	Format
v33_89_95.pdf		295Kb	Adobe PDF	2556	View/Open

Loading...