Chia Nan University of Pharmacy & Science Institutional Repository:Item 310902800/1253
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    Title: 月青基三乙酸鈉與α-甲基苯乙烯聚合反應之研究
    Authors: 林彰泰;劉孟春
    Contributors: 醫藥化學系
    Keywords: 月青基三乙酸鈉
    α-甲基苯乙烯
    鈰離子
    微結構
    Date: 2002
    Issue Date: 2008-06-30 14:41:59 (UTC+8)
    Publisher: 台南縣:嘉南藥理科技大學醫藥化學系
    Abstract: 月青基 三 乙 酸 鈉 (tirsodium nitrilotriacetate)可與金屬離子螯合,形成穩定的錯合物,並增強金屬離子催化活性,乃成效顯著之均勻系觸媒,但易殘留於生物中而有污染品質之虞。為改善均勻觸媒之缺點,本實驗利用NTA與α-甲基苯乙烯在60℃氮氣條件下以鈰離子為起始劑進行聚合反應合,形成具螯合基之不均勻系觸媒,其可與金屬離子強力結合,避免離子流失,同時具反應催化活性,產物的分離純化簡單與觸媒易回收之優點。並藉FTIR,NMR儀器測定其化學結構,導縯可能之聚合反應機構。
    Relation: 計畫編號:CNAC9114
    Appears in Collections:[Dept. of Food & Drug Industry and Inspective Technology] Chna Project

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