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    標題: Mixed-Valence Properties in L-type Complexes
    作者: Ju-Ling Lin(林如玲)
    Yuan Jang Chen(陳元璋)
    貢獻者: Department of Chemistry, Fu Jen Catholic University
    關鍵字: mixed-valence chemistry
    intervalence transfer
    superexchange coupling
    日期: 2008-07
    上傳時間: 2017-12-04 15:54:47 (UTC+8)
    摘要: Mixed-Valance chemistry in ruthenium is the transition metal choice to study electron transfer or exchange because low spin d5-d6 center from relatively stable coordinate complexes.1-3 Hush published the well-known basis of mixed-valence chemistry which focused on the two-state model.4 Creutz, Newton and Sutin reported a new aspect of the superexchange coupling model with the three-state system.5,6 Few reports provided significant points of real systems for superexchange coupling.7-9 The focus of this report is the synthesis and study of L-type tri-ruthenium complexes that exhibit interesting intervalence absorption and strong comproportionation between terminal metal centers. The electochemistry of △E1/2 between terminal centers for RU3(1) and Ru3(2) ranged between 0.12 and 0.13V.
    關聯: 第五屆海峽化學、生物及材料研討會,起迄日:2008/07/21-2008/07/22,地點:嘉南藥理科技大學
    顯示於類別:[藥理學院] 2008第五屆海峽化學、生物及材料研討會

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