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    Please use this identifier to cite or link to this item: http://ir.cnu.edu.tw/handle/310902800/30484

    標題: Preparation of Polypeptide via Living Polymerization of Z-Lys-NCA Initiated by Platinum Complexes
    作者: Ya-Liu Peng
    Shu-Ling Lai
    Chu-Chieh Lin
    貢獻者: Department of Chemistry, National Chung Hsing University
    College of Design, Ling Tung University
    日期: 2008-07
    上傳時間: 2017-12-04 15:53:59 (UTC+8)
    摘要: Two novel platinum complexes, ((dppe)Pt(MBS-O) (2a) and (dppe)Pt(MBS-NH) (2b) have been synthesized and structurally characterized. Experimental results show that compound 2b is an efficient initiator toward ring opening polymerization of NCA yielding polypeptides with narrow PDls (1.07-1.19).By comparing the activity of complexes 2a with that of 2b, the mechanism for polymerization of NCA initiated by an amido-sulfonamidate is proposed.
    關聯: 第五屆海峽化學、生物及材料研討會,起迄日:2008/07/21-2008/07/22,地點:嘉南藥理科技大學
    Appears in Collections:[藥理學院] 2008第五屆海峽化學、生物及材料研討會

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