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    Please use this identifier to cite or link to this item: http://ir.cnu.edu.tw/handle/310902800/27947


    標題: Thermal Properties Improvement of Bismaleimide Resin by a New Phosphorus-containing Polycyclic Bismaleimide
    作者: Tsai, Pai-Feng
    Kuo, Wen-Lung
    Shau, Min-Da
    貢獻者: 生物科技系
    職業安全衛生系
    關鍵字: Bismaleimide
    Flame Retardancy
    Polycyclic
    Phosphorus
    Thermal Properties
    日期: 2013-02
    上傳時間: 2014-05-26 10:50:10 (UTC+8)
    出版者: Wiley-V C H Verlag Gmbh
    摘要: A new phosphorus-containing polycyclic bismaleimide resin (BMPI) was prepared by the reaction of bis(3-maleimidophenyl) methylphosphine oxide (BAMP) with benzene-1,2,4,5-tetracarboxylic dianhydride (BTD) and maleic anhydride (MA). BMPI was confirmed by infrared (IR), H-1- and C-13-NMR spectroscopies. Its thermal properties were carried out by a differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA) that revealed that the polymers have excellent thermal properties in the high temperature region and a high char yield of up to 53 similar to 65%. Furthermore, three conventional bismaleimide resins were prepared from different phosphorus-free bismaleimides for comparison, e.g. 4,4'-bismaleimidodiphenylmethane (BDM), 4,4'-bismaleimidodiphenylether (BDE), 4,4'-bismaleimidodiphenylsulfone (BDS).
    關聯: Journal of the Chinese Chemical Society, v.60 n.2, pp.229-234
    Appears in Collections:[生物科技系(所)] 期刊論文
    [職業安全衛生系(含防災所)] 期刊論文

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