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    Please use this identifier to cite or link to this item: http://ir.cnu.edu.tw/handle/310902800/27661


    標題: Synthesis and characteristics of poly(methacrylic acid-co-N-isopropylacrylamide)/Nano ZnO thermosensitive composite hollow latex particles
    作者: Pan, Tzu-Yu
    Lee, Yuan-Po
    Chu, Chun-Hsun
    Chen, Yi-Hsuan
    Tsai, Chen-An
    Lee, Chia-Fen
    貢獻者: 化妝品應用與管理系
    關鍵字: Thermosensitive
    Soapless Emulsion Polymerization
    Zno
    日期: 2012-04-03
    上傳時間: 2014-03-21 16:16:49 (UTC+8)
    出版者: Elsevier Sci Ltd
    摘要: In this work, the poly(methacrylic acid-co-N-isopropylacrylamide)/Nano ZnO thermosensitive composite hollow latex particles was synthesized by three processes. The first process was to synthesize the poly(methyl methacrylate-co- methacrylic acid) (poly(MMA-MAA)) copolymer latex particles by the method of soapless emulsion polymerization. The second process was to polymerize MAA, N-isopropylacrylamide (NIPAAm) and N,N'-Methylenebisacrylamide (MBA) in the presence of poly(MMA-MAA) latex particles to form the linear poly(MMA-MAA)/crosslinking poly(MAA-NIPAAm) core-shell latex particles, and then the core-shell latex particles were heated in the presence of ammonia solution to form the poly(MAA-NIPAAm) thermosensitive hollow latex particles. In the third process, the poly(MAA-NIPAAm) hollow latex particles reacted with ZnO nanoparticles to form the poly(MAA-NIPAAm)/ZnO thermosensitive composite hollow latex particles on which the ZnO nanoparticles were adsorbed. Besides, a novel process was used to synthesize the poly(MAA-NIPAAm)/ZnO composite latex particles in which the ZnO nanoparticles were encapsulated. The effects of various variables on the morphology of poly(MAA-NIPAAm)/ZnO composite hollow latex particle were studied. (C) 2012 Elsevier Ltd. All rights reserved.
    Appears in Collections:[化妝品應用與管理系(所)] 期刊論文

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