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    Please use this identifier to cite or link to this item: http://ir.cnu.edu.tw/handle/310902800/25344


    標題: Mineralization of 2,6-dimethylaniline by photoelectro-Fenton process
    作者: Nalinrut Masomboon
    Chavalit Ratanatamskul
    Ming-Chun Lu
    貢獻者: 環境資源管理系
    關鍵字: 2,6-Dimethylaniline
    Advanced oxidation processes
    Photoelectro-Fenton process
    Hydroxyl radical
    日期: 2010-08
    上傳時間: 2012-05-31 14:49:40 (UTC+8)
    摘要: A new approach to promoting ferric reduction efficiency using electrochemical, photoreduction and photo-assisted electrochemical processes has been developed. The use of UVA irradiation and electric current as electron donors can efficiently initiate a Fenton reaction called the photoelectro-Fenton process. 2,6-Dimethylaniline was the target compound in this study. Parameters including initial pH, ferrous ion dosage, hydrogen peroxide concentration, the electric current applied and the number of UVA lamps used were investigated to evaluate the performance of the photoelectro-Fenton process. The removal efficiencies of 2,6-dimethylaniline, COD, TOC and initial degradation rate were determined in this study. The optimum condition for 1 mM of 2,6-dimethylaniline degradation was achieved when using 1 mM of ferrous ions, 20 mM of hydrogen peroxide at pH 2 and 2 A of electric current applied with four UVA lamps used. The energy cost, reaction mechanism and intermediates identification of 2,6-dimethylaniline degradation have also been determined in this study.
    關聯: Applied Catalysis A: General 384(1-2):p.128-135
    Appears in Collections:[環境資源管理系(所)] 期刊論文

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