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    Please use this identifier to cite or link to this item: http://ir.cnu.edu.tw/handle/310902800/25322


    標題: Adsorption of Copper (II) and Lead (II) ions from Aqueous Solution on Chitosan-Coated Sand
    作者: Meng-Wei Wan
    Chi-Chuan Kan
    Buenda D. Rogel
    Maria Lourdes P. Dalida
    貢獻者: 環境工程與科學系
    關鍵字: Chitosan
    Adsorption
    Copper
    Lead
    Sand
    Permeable reactive barrier
    日期: 2010-05
    上傳時間: 2012-05-31 09:57:32 (UTC+8)
    摘要: Biodegradable material, known as chitosan-coatedsand (CCS), was utilized for removal ofcopper (II) andlead (II) ions in water. Batch experiments were conducted to investigate the adsorption effect under different initial concentration (Co = 100, 500, 1000 and 2000 mg/L), solution pH (2, 3, 4, 5 and 6), and contact time (0.5, 1, 2, 4, 6, 12 and 24 h). Desorption studies were performed using diluted HCl solution (pH 1 and 3) and tap water (pH 7) on adsorbed metal ions. Langmuir and Freundlich adsorption models were used to describe static isotherms and constants. The data fitted well with Langmuir model at Qmax value of 8.18 and 12.32 mg/g CCS for Cu(II) and Pb(II) ions at 4 h contact time, respectively. Kinetic studies followed the pseudo second-order reaction, which indicated that the chemical sorption is the rate-limiting step. Results of desorption process signified potential for recovering metal ionsfrom CCS.
    Appears in Collections:[環境工程與科學系(所)] 期刊論文

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