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    Please use this identifier to cite or link to this item: http://ir.cnu.edu.tw/handle/310902800/25150


    標題: Synthesis and properties of new (μ-oxo)bis[trichloroferrate(III)] dianion saltsincorporated with dicationicmoiety
    作者: Jui-Cheng Chang
    Wen-Yueh Ho
    I-Wen Sun
    Yu-Kai Chou
    Hsin-Hsiu Hsieh
    Tzi-Yi Wu
    Shih-Shin Liang
    貢獻者: 化粧品應用與管理系
    關鍵字: Dication
    Ionic liquid
    TGA curves
    X-ray single crystal
    Iron(III) anion
    Diferrate anion
    Magnetic susceptibility
    Magnetic coupling constant
    日期: 2010-10
    上傳時間: 2012-03-29 13:46:04 (UTC+8)
    摘要: New (μ-oxo)bis[trichloroferrate(III)] dianions-based ionic compounds that contain various counterdications were synthesized and characterized with regards to their crystal structures, thermal properties, and magnetic susceptibility. These salts are soluble in polar solvents such as methanol and water. The melting point of these compounds is affected by the dication following the order of triphenylphosphinium > pyridinium > imidazolium dications, and symmetrical dicationicsalts > unsymmetrical ones. In these compounds, the trichloroferrate dianion exists in either a linear or a bent form, which is affected by the dications. Interestingly, the dicationic diferrate compounds show magnetic coupling constants fairly smaller than those reported in literature for diferrate salts in which monocations are the counterion. Furthermore, unlike the diferrate salts associated with separate monocations, the linear diferrate dicationic compounds show magnetic coupling constant lower than that of bent diferrate dicationicsalts.
    關聯: polyhedron 29(15):p.2976-2984
    Appears in Collections:[化妝品應用與管理系(所)] 期刊論文

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