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    Please use this identifier to cite or link to this item: http://ir.cnu.edu.tw/handle/310902800/24400


    標題: 3-取代基-4-甲醛基雪梨酮之極譜及紫外線吸收光譜之研究
    Polarographic and UV Spectrophotometric Studies of 3-Substituted-4-Formylsydnones
    作者: 田憲儒
    王來好
    葉茂榮
    貢獻者: 成功大學 化學研究所
    日期: 1987
    上傳時間: 2011-10-24 14:27:26 (UTC+8)
    摘要: 本研究係利用極譜儀研究五種3一取代基一4一甲醛基雪梨酮在滴汞電極(dropping mercury electrode )之還原現象 ; 包括酸度,反應物濃度,溶劑與支持電解質等對還原行為之影響。並由半波電位,極限電流與pH值之關係,探討在電極的反應機構。由極譜法與紫外線吸收光譜法證實3一取代基一4一甲醛基雪梨酮的還原電位符合修飾過的Hammett式。
    The reducing behavious of five 3-substituted-y-formylsydnones were studied with dropping mercury electrode including the influences of acidity, concentration, solvent and supporting electolyte. And the possible reaction mechanisms were discussed by the relations of half-wave potentials, limiting current and pH-values. According to the results of the polarographic and UV spectrophotometric methods,the reducing potentials of 3-substituted-4-formylsydnones obey the modified Hammett equation.
    關聯: 嘉南學報 13: A48-A58 轉載 化學 44(4) : p.132-142 (1986)
    Appears in Collections:[嘉南學報] 13期 (1987)

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