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    Please use this identifier to cite or link to this item: http://ir.cnu.edu.tw/handle/310902800/24275


    標題: Dissociation Kinetics of Aqua[(1SR, 4RS, 7RS, 8SR, 11RS, 14RS)-5,5,7,12,12,14'-Hexamethyl-1,4,8,11-Tetraazacyclotetradcane]Copper(Ⅱ) (Red) Cation in Strongly Acidic, Aqueous Media
    作者: Lien-Huei Chen
    Chung-Sun Chung
    貢獻者: 應用化學科
    關鍵字: Kinetics of [Cu(tet b)(H2O)(red)]2+
    日期: 1989
    上傳時間: 2011-09-14 15:37:38 (UTC+8)
    摘要: In order to investigate the effect of structure variation upon complex dissociation rate constants, the kinetics of the dissociation of (C-rac-5,5,7,12,12,14-hexamethyl-1,4,811-tetraazacyclotetradecane) copper(II) (red) cation has been examined spectrophotometrically at 25.0℃ in 0.1-5.0 M HNO3. The possible pathways for the cleavages of the copper-nitrogen bonds, the factors influencing the dissociation rates, and the factors affecting the relative importance of each of these possible pathways are considered.
    關聯: 嘉南學報 15 : p.A7-A15 轉載 Journal of the Chinese Chemical Society 36(3),p.195-203 (1989)
    Appears in Collections:[嘉南學報] 15期 (1989)
    [醫藥化學系 ] 期刊論文

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