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    Please use this identifier to cite or link to this item: http://ir.cnu.edu.tw/handle/310902800/19065


    標題: 1-乙烯咪唑在室溫離子液體中之反向原子轉移自由基聚合
    Reverse Atom Transfer Radical Polymerization of 1-Vinylimidazole in Room Temperature Ionic Liquids
    作者: 何文岳
    劉家全
    呂昆霖
    楊彩秀
    魏騰芳
    劉瑞珍
    許智偉
    貢獻者: 化粧品應用與管理系
    化粧品科技研究所
    保健營養系
    營養與保健科技研究所
    關鍵字: 離子液體
    反向原子轉移自由基聚合
    1-甲基咪唑
    1-乙烯咪唑
    Ionic liquid
    Reverse atom transfer radical polymerization
    1-Methylimidazole
    1-Vinylimidazole
    日期: 2007
    上傳時間: 2009-04-12 09:56:10 (UTC+8)
    摘要: 本研究利用室溫離子液體為溶劑,以1-乙烯咪唑為反應單體進行反向原子轉移自由基聚合反應之研究。在室溫離子液體的合成上,以1-甲基咪唑為原料,經由烷基化與陰離子交換反應後,製備出5種室溫離子液體。接著以此室溫離子液體為溶劑,利用氯化銅(II)為催化劑進行1-乙烯咪唑單體的反向原子轉移自由基聚合反應研究,由反應之結果顯示:聚合物分子量之分布範圍主要受到離子液體黏度的影響,而相同陰離子結構的離子液體其黏度越低,則反應後聚合物分子量之分布會越狹窄。
    This research was about reverse atom transfer radical polymerization of 1-vinylimidazole in room temperature ionic liquids. Five room temperature ionic liquids were synthesized by using 1-methylimidazole as starting material, and CuCl2 was selected as cat
    關聯: 嘉南學報(科技類) 33期:p.89-95
    Appears in Collections:[嘉南學報] 33 期 (2007)
    [化妝品應用與管理系(所)] 期刊論文
    [保健營養系(所) ] 期刊論文

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