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    Please use this identifier to cite or link to this item: http://ir.cnu.edu.tw/handle/310902800/1850

    標題: 2-溴芳香基烯晴的自由基環合反應位置選擇性之研究
    Studies on the Free-Radical Regioselective Cyclization of 2-Bromoaryl Alkenenitriles
    作者: 楊朝成
    Chau-Chen Yang
    貢獻者: 化妝品應用與管理系
    關鍵字: 溴苯氧基烯晴
    Bromophenoxy alkenenitrile
    Methyl bromoanilino alkenenitrile
    Bromophenylthio alkenenitrile
    Free radical
    日期: 1999
    上傳時間: 2008-07-18 16:22:55 (UTC+8)
    出版者: 台南縣:嘉南藥理科技大學化妝品應用與管理系
    摘要: 本計畫主要研究2-溴芳香基烯晴化合物藉由三丁基錫烷在AIBN催化下,形成芳香基自由基,在氰基位置進行分子內加成反應之後,再與雙烯進行一次環合反應並進一部氧化得到一系列之雜環化合物。
    This Thesis describes the regiochemistry Intramolecular cyclization of 2-(bromophenylthio)-2,4-alkadienenitriles 3, 5 and 2-(2-bromophenoxy)-2,4-alkadienenitriles 4, 6, which treatment with Bu3SnH reduced to generate an aryl free radical and underwent cyclization at the cyano group to give iminoradical. The iminoradical had the potential to undergo electrocyclization and subsequent oxidative aromation to afford heterocyclic compounds (Such as 5H-benzo[4,5]thiolo[3,2-b]azines, 5H-benzo[4,5]oxolo[3,2-b] azines).
    關聯: 計畫編號:NSC88-2113-M-041-003
    Appears in Collections:[化妝品應用與管理系(所)] 科技部計畫

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