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    Please use this identifier to cite or link to this item: http://ir.cnu.edu.tw/handle/310902800/1842


    標題: 以含催化性有機金屬的厭水性電極電解土壤中鹵化有機污染物以及萃取與電解流程自動化的研究
    Study of the Electrolysis of Organichalides Pollutants on Soils at a Hydrophobic Electrode Containing Catalytic Organicmetal and the Automation of the Operative Processes
    作者: 張朝明
    Chur-Mi Chang
    貢獻者: 醫藥化學系
    關鍵字: 鹵化有機物
    有機金屬化合物
    萃取
    電解
    Organohalide
    Organometallic compound
    Extraction
    Electrolysis
    日期: 1998
    上傳時間: 2008-07-18 16:08:18 (UTC+8)
    出版者: 台南縣:嘉南藥理科技大學醫藥化學系
    摘要: 由於以往在工常上及農業上大量的使用鹵化有機物,而這類汙染物質通常是與土壤及水沈積物結合而存在,加上在土壤及水沈積物中其自然分解速率緩慢而纍積於其中,使得鹵化有機汙染物普遍存在目前的環境中。本研究利用自製的鉛電極以及含催化性金屬錯合物的厭水性鉛複合電極,分別探討二溴聯苯、二氯聯苯及五氯氛的CV電化學性質。其次,利用添加方式探討超音波振盪萃取土壤中二溴聯苯、二氯聯苯及五氯氛的萃取效率。此外,利用流動電解槽結合超音波振盪萃取設計完成一流動電解系統。最後,利用ADDA及I/O介面卡及PC完成電解流程自動化的設計。
    Organohalides pollutants are ubiquitous in our environment from past industrial and agricultural usage. Organohalides in the environment are often associated with soils and aquatic sediments. The quantity of organohalides in the environment increased with the time due to the quite slow rate of natural dechlorination in soils and sediments. In this studies, a hydrophobic composite electrode with a organometal catalyst was prepared. The electrochemical characteristics of three organohalides were studied by the detection of cyclic voltametry with the cathode of lead electrode and composite electrode. The design of automatic extractive and electrolytic system, and the extractive and electrolytic efficiencies of organohalides in soil were described.
    關聯: 計畫編號:NSC87-2113-M041-003
    Appears in Collections:[醫藥化學系 ] 國科會計畫

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